Making window frames
I find windows difficult to make accurately, probably a result of advancing years and failing eyesight. I'm not about to go spending money on fancy etched brass things and resin casting seems to have passed me by, so scratch building is the only way.
Here is the method I use. The photographs are fairly self explanatory.
It goes without saying (but I'll say it anyway) that you should mark out your proposed window frame accurately on graph paper or similar, you could use a plan, if you have one, or even a photograph.
If you have a laser printer, you can design your window frames in the graphics package of your choice - I use and recommend Xara Designer - and print them out. You could kill two birds with one stone by printing them out onto clear OHP film.
The glazing material usually comes from dis-guarded packaging, the example here is an offcut of camera screen protector, but obviously it can be anything you can find.
Many of my earlier buildings had windows made using thin strips of card/banner tape laminate for the frames and glazing bars, however styrene strip is far easier to handle and get accurate joints.
I make my own self adhesive microstrip simply with banner tape and 0.010" styrene sheet. Stick the tape to one side and slice it into strips with a straight edge and a scalpel. Cut slowly and gently to avoid the strip curling up or bending.
I lay down the outer frame first, followed by the either the horizontal or vertical glazing bars depending on the type of window - you can cover the joints with the 'moulding' you add later so you need to think about the construction of a real window at this point. Some windows, sash windows for example, have to be built in several layers
The tool I use for cutting the ends of the microstrip is shown in the first photograph. A chisel blade, it will chop straight through several layers of thin card or styrene in one firm vertical press. If you are going to buy one, get a decent trusted make, I think that one was made by Exacto -
I stick the remaining glazing bars on as a whole length, then clip out the bits where they cross with my trusty chisel tool. as you can probably see, the hard bit is getting the glazing bars nice and straight.
Getting the 45° mitres in the corners is a bit of a cheat, overlap the two strips and cut through both at once, then remove the waste bits, that way the angle doesn't have to be perfect.

A few tips.
If I'm not going to detail the interior of the building, or I just don't want the windows to be too transparent, I rub the back with a bit of fine wet n dry or a track rubber. Rubbing in one direction only and at an angle leaves the 'glass' shiny but less see though.
If you chose a glazing material which isn't affected by solvent, you can wash over the frame with MekPac or whatever is your styrene solvent of choice, this softens the edges of the microstrip and helps to hide the joints. It doesn't seem to affect the adhesive used on banner tape.
Once in situ in the building, I usually flood the whole window with 50% PVA/water mix. This fills any gaps betwixt the building wall and window frame, amalgamates the whole thing together and softens it down nicely. a spot of washing up liquid in the mixture helps it to flow.
You can make a quite good attempt at leaded windows by printing the lead parts or cames as they are called onto OHP film.